Phase transitions and related electrochemical performances of Li-Rich layered cathode materials for high-energy lithium ion batteries
2018
Abstract The present work systematically probes and tracks the phase transition of Li-rich layered Li[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 (marked as LMNCO) by using an ex-situ chemical activation that is realized through ion-exchange and post-annealing processes, in order to understand related electrochemical performances of Li-rich cathode materials for advanced lithium-ion batteries. Ion exchanges of H + -Li + and subsequent TBA + -H + (TBA: tetrabutylammonium) in LMNCO are carried out, resulting in its layered-to-spinel phase transition after optimal heat treatments. The resultant compound shows a Li 4 Mn 5 O 12 -type spinel structure. This converted spinel cathode material can deliver discharge capacities higher than 300 mAh/g at 0.1 C and 200 mAh/g at 1 C (1 C = 250 mA/g), respectively, and also exhibits better cycling stability and rate capability in comparison with pristine layered LMNCO and other derivatives. This work offers a feasible route to study all changes of morphologies, crystal structures, chemical compositions, surface areas and related electrochemical lithium storage behaviors during phase transitions of Li-rich layered cathode materials, and thus provides insights on optimizing electrochemical performances for high-energy and high-power lithium ion batteries.
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