application as gas sensors

This paper describes the morphology, stoichiometry, microstructure and gas sensing properties of nano clustered SnO x thin films prepared by Sn evaporation followed by the Rheotaxial Growth and Thermal Oxidation (RGTO) process. Electron microscopy was used to investigate, in detail, the evolution of the films as the oxidation temperature was increased. The results showed that the contact angle, perpendicular height, volume and microstructure of the clusters all changed significantly as a result of the thermal oxidation processes. Electron diffraction and X-ray photoelectron spectroscopy measurements revealed that after oxidation at a temperature of 600 oC, the Sn clusters were fully transformed into porous 3-dimensional polycrystalline SnO 2 clusters. Based on these results, a prototype SnO 2 sensor was fabricated and sensing measurements were performed with H 2 and NO 2 gases. At operating temperatures of 150 oC - 200 oC the film produced measurable responses to concentrations of H 2 as low as 600 ppm and NO 2 as low as 500