Bis(trimethylsilyl)selenide in the Selective Synthesis of β-Hydroxy, β-Mercapto, and β-Amino Diorganyl Diselenides and Selenides Through Ring Opening of Strained Heterocycles.

Damiano Tanini,Alessandro Degl'Innocenti,Antonella Capperucci

Bis(trimethylsilyl)selenide in the Selective Synthesis of β-Hydroxy, β-Mercapto, and β-Amino Diorganyl Diselenides and Selenides Through Ring Opening of Strained Heterocycles.

2015

Damiano Tanini
Alessandro Degl'Innocenti
Antonella Capperucci

A novel approach to the synthesis of β-substituted dialkyl diselenides and selenides is described through reaction of bis(trimethylsilyl)selenide with epoxides, thiiranes, and aziridines catalyzed by tetrabutylammonium fluoride.

Keywords:

Trimethylsilyl
Selenide
Tetrabutylammonium fluoride
Medicinal chemistry
Catalysis
Organic chemistry
Chemistry

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