Synthesis and properties of monodisperse oligofluorene-functionalized truxenes: highly fluorescent star-shaped architectures.
2004
This paper describes the strategy toward novel monodisperse, well-defined, star-shaped oligofluorenes with a central truxene core and from monofluorene to quaterfluorene arms. Introduction of solubilizing n-hexyl groups at both fluorene and truxene moieties results in highly soluble, intrinsically two-dimensional nanosized macromolecules T1−T4. The radius for the largest oligomer of ca. 3.9 nm represents one of the largest known star-shaped conjugated systems. Cyclic voltammetry experiments reveal reversible or quasi-reversible oxidation and reduction processes (Eox = +0.74 to 0.80 V, Ered = −2.66 to 2.80 eV vs Fc/Fc+), demonstrating excellent electrochemical stability toward both p- and n-doping, while the band gaps of the oligomers are quite high (EgCV = 3.20−3.40 eV). Close band gaps of 3.05−3.29 eV have been estimated from the electron absorption spectra. These star-shaped macromolecules demonstrate good thermal stability (up to 400−420 °C) and improved glass transition temperatures with an increase i...
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