Total synthesis of (-)-isoaltholactone
2013
A short and efficient stereoselective synthesis of a styryllactone (−)-isoaltholactone has been achieved in seven steps and 33% overall yield, starting from the readily available carbohydrate D-mannose. The key steps of our synthesis involve intramolecular tetrahydrofuran cyclization and one-pot acetonide deprotection-lactonization.
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