Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials
2012
Nickel(II) complexes with double alkyl chain functionalized N-heterocyclic carbene (NHC) ligands, [NiCl2(C12MIM)2] and [NiCl2(C12C12IM)2], where C12MIM = 1-dodecyl-3-methylimidazolin-2-ylidene (1) and C12C12IM = 1,3-didodecylimidazolin-2-ylidene (2), have been prepared and fully characterized by 1H NMR, 13C NMR, and CHN elemental analyses. Furthermore, we have developed a system, in which double long alkyl chain derivatized Ni–NHC complexes are dissolved in the related ionic liquid crystalline 1,3-didodecylimidazolium tetrafluoroborate, [C12C12IM][BF4], to form pre-organized structures for enhanced reactivity. Remarkably, differential scanning calorimetry, polarized optical microscopy, and temperature-programmed IR reflection absorption spectroscopy performed on a mixture of 10 wt% Ni complexes in [C12C12IM][BF4] demonstrate that this system retains an ionic liquid crystalline phase; even after immobilization onto a silica-100 support with pore filling α = 1.
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