Methanol oxidation at platinized copper particles prepared by galvanic replacement

Bimetallic Pt-Cu particles have been prepared by galvanic replacement of Cu precursor nanoparticles, upon the treatment of the latter with a chloro-platinate acidic solution. The resulting particles, typically a few tens of nm large, were supported on high surface area carbon ( Vulcan ®  XC–72R, Cabot) and tested as electrodes. Surface electrochemistry in deaerated acid solutions was similar to that of pure Pt, indicating the existence of a Pt shell (hence the particles are denoted as Pt(Cu)). Pt(Cu)/C supported catalysts exhibit superior carbon monoxide and methanol oxidation activity with respect to their Pt/C analogues when compared on a per electroactive surface area basis, due to the modification of Pt activity by Cu residing in the particle core. However, as a result of large particle size and agglomeration phenomena, Pt(Cu)/C are still inferior to Pt/C when compared on a mass specific activity basis.