Uptake of n-Hexane, 1-Butene, and Toluene by Au/Pt Bimetallic Surfaces: A Tool for Selective Sensing of Hydrocarbons under High-Vacuum Conditions

The dissociative adsorption and decomoposition on a range of metal surfaces of an alkane, an alkene, and an aromatic, all representative of species present in an important technological application, has been studied under conditions relevant to selective gas sensing based on solid electrolyte potentiometry. At 870 K, pure polycrystalline Pt surfaces do not discriminate between n-hexane, toluene, and 1-butene:  graphitic carbon accumulation occurs at almost the same rate. However, by varying the composition of polycrystalline bimetallic Pt/Au surfaces, good discrimination between these species can be achieved. Thus at a nominal surface composition of ∼75% Au (XPS), good selectivity toward 1-butene and toluene uptake is achieved, with essentially no response to n-hexane. At ∼80% Au the system is selective to 1-butene alone. Particular merits of these systems include good high-temperature stability and good tunability of their chemical selectivity. This makes possible the development of array devices in whic...