Studies on the selectivity between glycosylation and intermolecular aglycone transfer of thioglucoside in synthesis of lactose derivatives

Marie Kato,Go Hirai,Mikiko Sodeoka

Studies on the selectivity between glycosylation and intermolecular aglycone transfer of thioglucoside in synthesis of lactose derivatives

2011

Marie Kato
Go Hirai
Mikiko Sodeoka

In the reaction with the thioglycoside acceptor (II), electron-donating groups on the galactose donor (I) can prevent the aglycone-transfer (AGT) reaction.

Keywords:

Lactose
Aglycone
Galactose
Acceptor
Biochemistry
Chemistry
Intermolecular force
Glycosylation
Organic chemistry
Selectivity
Stereochemistry
benzyl ether

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