A kind of Ludox/polyacrylate dispersion of high silicon content and preparation method thereof

2014 
Ludox/polyacrylate dispersion that the invention discloses a kind of high silicon content and preparation method thereof.The method uses water-soluble macromolecule that Ludox is carried out physical modification, modified Ludox and acrylic ester monomer is carried out in-situ polymerization and prepares Ludox/polyacrylate dispersion.In terms of mass fraction, the formula of raw material consists of: deionized water 50~70 parts, Ludox 5~30 parts, water-soluble macromolecule 0.01~0.5 part, acrylic ester monomer 20~53 parts, methacrylic acid or acrylic acid 1~5 parts, emulsifying agent 1~5 parts, initiator 0.1~0.5 part, pH buffer agent 0.1~0.5 part;With SiO 2 Meter, in emulsion, silicone content accounts for the 5~30% of whole solid content;Latex particle size is 60~100nm;Carboxyl on Inventive polymers strand and hydroxyl, SiO 2 The hydroxyl on micelle surface can occur esterification and crosslinking, makes the hardness of film reach more than 5H, and has prominent resistance to water and weatherability.
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