1-Phosphino-2-sulfenylferrocenes: Efficient Ligands in Enantioselective Palladium-Catalyzed Allylic Substitutions and Ring Opening of 7-Oxabenzonorbornadienes.

Julian Priego,Olga García Mancheño,Silvia Cabrera,Ramón Gómez Arrayás,Tomás Llamas,Juan C. Carretero

1-Phosphino-2-sulfenylferrocenes: Efficient Ligands in Enantioselective Palladium-Catalyzed Allylic Substitutions and Ring Opening of 7-Oxabenzonorbornadienes.

2003

Julian Priego
Olga García Mancheño
Silvia Cabrera
Ramón Gómez Arrayás
Tomás Llamas
Juan C. Carretero

The readily available 1-phosphino-2-sulfenylferrocenes 1 provide very high enantioselectivities in Pd-catalyzed allylic substitution reactions and alkylative ring opening of 7-oxabenzonorbornadiene with dialkylzinc reagents.

Keywords:

Enantioselective synthesis
Allylic rearrangement
Palladium
Organic chemistry
Chemistry
Catalysis
Ligand

Correction
Source
Cite
Save
Machine Reading By IdeaReader

References

Citations