A Gold-Catalyzed [4 + 3]-Cycloaddition of Functionalized Dioxines.

Michael Harmata,Chaofeng Huang

A Gold-Catalyzed [4 + 3]-Cycloaddition of Functionalized Dioxines.

2010

Michael Harmata
Chaofeng Huang

Abstract Treatment of 5-silyloxydioxins with 5 mol % AuCl3/AgSbF6 in the presence of cyclopentadiene or furan results in the rapid formation of [4+3]-cycloadducts at room temperature.

Keywords:

Bridged compounds
Cycloaddition
Chemistry
Organic chemistry
Catalysis

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