Darstellung und Charakterisierung von Anthrylenmagnesium-Innerkomplexen

Preparation and Characterization of Inner Complexes of Anthrylenemagnesium Anthracene derivatives containing ether or amino groups in 9- or 9,10-position (1 – 10) react with magnesium to form new magnesium anthracene inner complexes (11 – 20). These complexes as well as their organic starting materials have been extensively characterized by spectroscopy and chemical means. It was found that solvent ligands which are present in all magnesium anthracene complexes known to date can be partially or totally replaced by inner complexation. For some of the new magnesium anthracene inner complexes the complex formation rates have been determined.