Tailor-Made Dispersion and Distribution of Stereocomplex Crystallites in Poly(l-lactide)/Elastomer Blends toward Largely Enhanced Crystallization Rate and Impact Toughness
2017
Stereocomplex (SC) crystallites, formed between poly(l-lactide) (PLLA) and poly(d-lactide), exhibit great potential to substantially enhance crystallization rate of PLLA-based materials as an eco-friendly nucleating agent. However, the nucleation efficiency of the SC crystallites is still far below an expected level, mostly on account of their strong aggregation tendency in PLLA/PDLA melts. Herein, taking PLLA/poly(ethylene-methyl acrylate-glycidyl methacrylate) (E-MA-GMA) blends as an example, we report a unique and facile strategy to control the dispersion and distribution of SC crystallites within the PLLA matrix by using elastomeric E-MA-GMA as carrier for the incorporation of PDLA. To do this, PDLA was first blended with E-MA-GMA or chemically grafted onto the E-MA-GMA. During subsequent melt-blending of PLLA and the E-MA-GMA/PDLA master batch, the PDLA chain clusters predispersed in the E-MA-GMA phase can gradually migrate into PLLA matrix and then collaborate with the matrix chains to form large am...
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