Hydrogen Bonding in ROH:R‘OH (R, R‘ = H, CH3, C2H5) Heterodimers: Matrix-Dependent Structure and Infrared-Induced Isomerization

The structure of ROH:R‘OH heterodimers (R, R‘ = H, CH3, C2H5) trapped in argon and nitrogen matrixes was examined through two approaches: 16O/18O isotopic substitution in water and methanol and infrared-induced isomerization. Isotopic substitution clearly shows that in N2 matrix the bigger molecule plays the role of proton donor (Type-I structure) and in Ar matrix that of proton acceptor (Type-II structure). This difference can be rationalized by considering the existence of weak OH···N2 hydrogen bonds stabilizing the less stable structure. Selective irradiations in the νOH region were carried out for the CH3OH:H2O and C2H5OH:H2O dimers. Type-I → Type-II interconversion was observed in N2 matrix while no effect was detected in Ar. Finally the hydrogen bond strength evolution within the nine ROH:R‘OH homo- and heterodimers was examined on both experimental and theoretical grounds. Experimentally this evolution was followed by considering the νOH frequency shifts of the proton donor subunit. Theoretically a...