Preparation and characterization of polyurethane (PU)/polyvinylidene fluoride (PVDF) blending membrane

AbstractIn order to improve the hydrophilicity and mechanical properties of polyvinylidene fluoride (PVDF) membrane, polyurethane (PU) was blended into PVDF casting solution and then PU/PVDF blending membrane was prepared via the method of thermally induced phase separation (TIPS). The properties and surface structure of the blending membrane were characterized by means of contact angle test, mechanical properties test, Fourier transform infrared spectroscopy (FTIR), atomic force microscope (AFM), and differential scanning calorimetry (DSC). The results showed that the contact angle of PVDF membrane was decreased from 85.71° of pure membrane to 66.46°of PU/PVDF blending membrane (PU of 2 wt.%), indicating that the hydrophilicity of blending membrane was significantly improved with the addition of PU. FTIR tests showed that the C=O stretching vibration absorption peak in aldehyde group (hydrophilic group) of PU/PVDF blending membrane was stronger than that of pure PVDF membrane, which can explain the incre...