Indium(I) Bromide-Mediated Regioselective Markovnikov Hydroselenation, Diselenation and Hydration of Terminal Alkynes with Diphenyldiselenide in Aqueous Media

Clovis Peppe,Ernesto Schulz Lang,Gabriela N. Ledesma,Lierson Borges de Castro,Olga Soares do Rego Barros,Paola A. Mello

Indium(I) Bromide-Mediated Regioselective Markovnikov Hydroselenation, Diselenation and Hydration of Terminal Alkynes with Diphenyldiselenide in Aqueous Media

2005

Clovis Peppe
Ernesto Schulz Lang
Gabriela N. Ledesma
Lierson Borges de Castro
Olga Soares do Rego Barros
Paola A. Mello

The indium(III) selenolate obtained from indium(I) bromide and diphenyldiselenide promotes, alternatively, the Markovnikov hydroselenation, diselenation or hydration of terminal alkynes, depending on the experimental conditions.

Keywords:

Markovnikov's rule
Regioselectivity
Indium(I) bromide
Polymer chemistry
Indium
Bromide
Aqueous solution
Diphenyldiselenide
Chemistry
Organic chemistry
aqueous medium

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