Synthesis of yeast extract-stabilized Cu nanoclusters for sensitive fluorescent detection of sulfide ions in water

Abstract In this work, we have presented a novel strategy to utilize as-synthesized yeast extract-stabilized Cu nanoclusters (Cu NCs) for sensitive and selective detection of S 2− . The fluorescence intensity of Cu NCs was enhanced significantly in the presence of both Na 2 S 2 O 8 and S 2− . By virtue of this specific response, a Cu NC-based fluorescent turn-on sensor was developed, which allows the detection of S 2− in the range of 0.02–0.8 μM with a detection limit of 10 nM. The enhancing mechanism was also discussed based on fluorescence decay, transmission electron microscopy (TEM) and dynamic light scattering (DLS) studies, indicating that S 2− enhanced the Cu NCs emission mainly through sulfide-induced aggregation of Cu NCs. Furthermore, we demonstrated the usability of the present approach for the detection of S 2− in water samples, which illustrates its great potential for the environmental monitoring and water quality inspection fields.