Cross-sectional control of boron contents and the microstructures of Co/Pd multilayer perpendicular magnetic recording media

The effects of cross-sectional modulated boron segregation on Co/PdB multilayer perpendicular magnetic recording media have been studied. Gradually reduced boron contents from thin PdB seed layer (33 at.%) to the top of the Co(0.2 nm)/PdB (0.8-nm) multilayer (12.5 at.% at the center of the multilayer) were successively achieved and confirmed by the depth-profile of X-ray photoelectron spectroscopy (XPS). Observed magnetic properties and magnetic force microscopy images suggested that this gradient diffusion supports reduction of intergrain exchange coupling and improvement of the magnetic properties. The signal-to-noise ratio over 22 dB was obtained at 450 kFCI in playback tests, in combination with amorphous cobalt boron soft-magnetic underlayer (SUL). It is suggested that these properties are brought by a combination of the dispersed nucleation sites with rich boron content in the initial layer and decreasing boron content during the growth of the multilayer. In addition, this simple medium, which consists of only three elements, Co, Pd, B, for the SUL, the seed layer, and the magnetic layer, has a very unique feature of the dull interfaces, observed by a transmission electron microscope.