Method for resourceful treatment of ammonia chloride wastewaters
2014
The invention relates to a method for resourceful treatment of ammonia chloride wastewaters. The method comprises the following steps: (1) respectively carrying out pretreatment on ammonia chloride wastewater with different concentrations for removing impurities; (2) carrying out reverse osmosis treatment on a clear liquor of the ammonia chloride wastewater, which is obtained in the step (1), with the concentration being lower than 0.5%; (3) mixing obtained reverse osmosis concentrated water with a clear liquid of the ammonia chloride wastewater, which is obtained in the step (2), with the concentration being higher than 0.5% so as to obtain ammonia chloride mixed wastewater; (4) carrying out conventional electrodialysis treatment on the obtained ammonia chloride mixed wastewater so as to obtain electrodialysis fresh water; (5) returning the obtained electrodialysis fresh water, carrying out reverse osmosis treatment the obtained electrodialysis fresh water to obtain electrodialysis concentrated water, and carrying out acid-alkali regeneration on the electrodialysis concentrated water by adopting bipolar membrane electrodialysis; and (6) converting ammonia chloride in the wastewater into hydrochloric acid and ammonium hydroxide by adopting the bipolar membrane electrodialysis to obtain low-concentration ammonia chloride wastewater, simultaneously returning the obtained low-concentration ammonia chloride wastewater and carrying out the conventional electrodialysis treatment on the obtained low-concentration ammonia chloride wastewater. According to the method, the resourceful treatment and the zero emission of the ammonia chloride wastewater can be really achieved.
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