Transannular Claisen rearrangement reactions for the synthesis of vinylcyclobutanes: formal synthesis of (±)-grandisol
2011
Unsaturated eight-membered lactones undergo decarboxylative and non-decarboxylative transannular Ireland–Claisen rearrangement reactions, to give substituted vinylcyclobutanes. A formal synthesis of (±)-grandisol is described.
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