Self-potential for monitoring soil remediation by smouldering: a proof of concept
2017
Near-surface soils contaminated with non-aqueous phase liquids, such as coal tar, crude oil, and
chlorinated solvents, remain a serious problem. Smouldering remediation is a technique now
being applied in the field for in situ destruction of non-aqueous phase liquids. Based on a selfsustaining
exothermic reaction, smouldering remediation generates a hot region (>400 °C) that
propagates through the subsurface. Self-potential is here considered for the first time as a nondestructive
means for monitoring the smouldering remediation process. First, a series of sandbox
experiments were conducted to investigate the magnitude of the thermoelectric coupling coefficient
(CTE) for different sand sizes, water contents, and heat sources. Measured CTE values ranged
from -0.47 mV/°C for coarse, water-saturated sand to -0.05 mV/°C for fine sand with a saturation
of 30%. Next, self-potential measurements were conducted during several laboratory smouldering
remediation experiments, examining the response as a function of both space and time. A
significant self-potential anomaly was observed on the surface during the smouldering period.
Moreover, the magnitude of the self-potential anomaly was demonstrated to be highly correlated
to the separation distance between the (moving) reaction front and the (stationary) self-potential
electrode positions. Overall, this research suggests that the self-potential method has a significant
promise as a non-invasive monitoring tool for in situ smouldering remediation of contaminated
sites.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
22
References
0
Citations
NaN
KQI