Designed morphotropic relaxor boundary ceramic exhibiting large electrostrain and negligible hysteresis

Abstract Electromechanical materials with large electrostrain and low hysteresis are strongly desired for high-precision actuator applications. Despite extensive studies for more than half a century, it is still a challenge to obtain large electrostrain and low hysteresis simultaneously due to the so-called strain-hysteresis trade-off. Here, we report a mechanism to overcome this trade-off: a ceramic composition locating at a morphotropic relaxor boundary (MRB), exhibits enhanced electrostrain and reduced hysteresis as compared with off-MRB compositions. The MRB, a composition-induced boundary separating two relaxors with different local polar symmetries, is attained by transforming an morphotropic phase boundary (MPB) in Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) through doping lanthanum. The performances of large electrostrain of 0.227% and negligible hysteresis of 3% of MRB composition are the best, as evidenced by occupying a virgin region in the strain-hysteresis chart of relaxor electromechanical ceramics. Moreover, this MRB ceramic maintains the large electrostrain and low hysteresis over a temperature range from 35 to -35 oC. The understanding of abnormal effects of MRB is established through combining microstructure observations and Landau theory analysis: the MRB composition with morphotropic nanodomain structure and higher degree of local structural heterogeneity shows a flatter energy profile with much lower energy barrier, thereby leading to a large electrostrain and negligible hysteresis. Our work demonstrates that the MRB is an effective mechanism to design relaxor materials with large electrostrain and low hysteresis simultaneously. We predict that more high-performance MRB electromechanical materials will be found in properly doped MPB systems.