On-surface synthesis of gold-coronene molecular wires
2020
Perchlorocoronene undergoes random dehalogenation at elevated temperatures, resulting in the formation of disordered gold-coronene complex on Au(111) surfaces. The dehalogenation can be guided by introducing intermolecular constraint from accompanying molecules coexisting on the surface. Owing to the intermolecular electrostatic interactions, gold-coronene wires are intercalated between the polyphenylene chains, which hinder the transverse dehalogenation and result in the improved tendency toward linear gold-coronene molecular wires.
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