Synthesis of alpha-Trifluoromethyl Ketones via the Cu-Catalyzed Trifluoromethylation of Silyl Enol Ethers Using an Electrophilic Trifluoromethylating Agent

Lun Li,chenqingyun,Yong Guo

Synthesis of alpha-Trifluoromethyl Ketones via the Cu-Catalyzed Trifluoromethylation of Silyl Enol Ethers Using an Electrophilic Trifluoromethylating Agent

2014

Lun Li
chenqingyun
Yong Guo

A method has been developed for the synthesis of alpha-trifluoromethyl ketones via the Cu-catalyzed trifluoromethylation of silyl enol ethers with an electrophilic trifluoromethylating agent, which produces a trifluoromethyl radical.

Keywords:

Electrophile
Trifluoromethyl
Enol
Trifluoromethylation
Organic chemistry
Catalysis
Photochemistry
Chemistry
Silylation

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