Microfluidic Preparation of Monodisperse Hollow Polyacrylonitrile Microspheres for ICF

Abstract Hollow polyacrylonitrile (PAN) microspheres can be used as fuel carriers in inertial confinement fusion (ICF) experiments due to their high tensile strength, low permeability to hydrogen isotopes, and resistance to tritium radiation corrosion. Monodisperse oil in water in oil (O1/W/O2) compound droplets were fabricated by the microfluidic technique and then monodisperse hollow polyacrylonitrile microspheres were prepared by the solvent evaporation method. The stability of O1/W/O2 compound droplets was improved by the addition of the surfactant (Dow Corning 749), which reduced the interfacial tension between the O2 phase and the W phase as well as the Laplace pressure on the surface of the compound droplets. The sphericity and the surface quality of the microspheres were also improved by the introduction of DMF droplets into the O2 phase to avoid emulsification, decreasing the DMF mass transfer rate. Therefore, fine monodisperse PAN microspheres with the diameter range of 700 μm - 800 μm were successfully prepared. Moreover, the size relationship between the compound droplets and the resulting microspheres was also evaluated, which can be used to predict the sizes of the PAN microspheres. The results provide a method for controllable preparation of monodisperse hollow PAN microspheres for ICF experiments.