Sulfur and potassium co-doped graphitic carbon nitride for highly enhanced photocatalytic hydrogen evolution

Abstract Modifying the structure of a photocatalyst to tailor its electronic and physicochemical properties is an effective approach for efficient photocatalysis. Herein, we demonstrate that co-doping non-metal (S) and metal (K) atoms into graphitic carbon nitride (g-C3N4) provides excellent visible-light photocatalytic hydrogen production activity of 8.78 mmol·g-1.h-1, which is 98 times higher than that of pristine g-C3N4 (0.09 mmol·g-1.h-1). The apparent quantum efficiency of the S+K-co-doped g-C3N4 reaches 70% at 420 nm. This outstanding photocatalytic performance attributed to an increased specific surface area from 6.78 to 74.23 cm3·g-1, which reduced the recombination of photogenerated charge carriers and enhanced conductivity. Various characterizations are undertaken to elucidate the S+K-co-doped g-C3N4 photocatalytic mechanism. Our work not only demonstrates a facile, eco-friendly and scalable strategy for the synthesis of S+K-co-doped g-C3N4 photocatalysts, but also opens a new avenue for the design of co-doped photocatalysts.