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The Rydberg States of S2

1995 
Abstract The absorption spectrum of S 2 has been observed down to 400 A on the SA63 line of SUPERACO (LURE) in Orsay, France. Two already reported Rydberg Series converging to the X 2 Π g ground state of S + 2 , π 4 u π 2 g X 3 Σ − g → π 4 u π g (π u np ) 3 Σ − u and π 4 u π 2 g X 3 Σ − g → π 4 u π g (σ u np ) 3 Π u , have been extended up to n = 10. Eight new series have been observed, giving ionization energies of 12.1247, 14.5562, 15.5737, 18.1067, 18.660, and 26.5838 eV, in good agreement with the values reported by Dyke et al. ( J. Chem. Soc. Faraday Trans. 7, 1026-1037, 1975) for the 2 Π u , 2 Σ − g , 2 Π u , 3 Σ − u , 2 Π u , and 2 Σ − g , ionic states, respectively.
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