Influence of oxidizing and Nitriding parameters on nitrogen concentration of electrical steels

Abstract The influence of oxidizing and nitriding parameters on the nitrogen concentration of grain-oriented electrical steels preliminary to the development of the final Goss texture was explored. Results show that the nitrogen enrichment is driven by a ferrite to austenite transformation during thermochemical treatments. Such a transformation is promoted by (i) a redistribution of ferrite-forming elements close to the surface during oxidizing prior to nitriding, (ii) the oxygen content within the oxide layer prior to nitriding, (iii) the temperature of oxidizing and nitriding, and (iv) the nitrogen enrichment during nitriding. Optimization of the nitrogen content, and thus the precipitation kinetics of alloying elements nitrides (e.g. inhibitors) required for the development of the final Goss texture can be controlled by an optimization of the oxide layer growth, the temperatures and gas mixture of nitriding.