Changes in Gold Composition and Gold-Associated Mineralogy with Time and Temperature at the Fort Knox Gold Deposit, Alaska - Abstract

In the gravity concentrate such gold is recognized by rare intergrown feldspar grains. This gold is of two types: extremely fine-grained, myrmekitic intergrowths of Bi° and Au° that likely formed by unmixing of Maldonite (Au2Bi) and rare grains of Maldonite. Both types are commonly surrounded by or associated with grains of Bi°. The myrmekitic gold is essentially pure, with fineness (lOOOx Au/(Au+Ag)) of 995-999, and distinctively bright yellow. Although Maldonite is unstable below ~100°C and should unmix, the intergrowths present are far too coarse to represent unmixing at 100C. We do not know why most Maldonite has experienced unmixing and some hasn't. Myrmekitic Au°-Bi° grains occur in the gravity concentrates both as isolated grains and as composites with Bi° (most commonly) or composites with lower-fineness gold. In the latter cases the fineness of the surrounding gold is typically zoned, with finess as high as 980 adjacent to the myrmekitic intergrowths and as low as 870 30-50 microns away. Such grains show visible changes in color from the bright yellow of nearly pure gold to more subdued pale yellow of silver-bearing gold. Gold grains that are not associated with Au-Bi myrmekite, do not, in general, display compositional zoning but are invariably associated with Bi-S + Te minerals and rarely with molybdenite (M0S2). Dozen of Bi-Te-S minerals are known; so far we have identified mostly non-stoichiometric minerals with compositions of Bi(Te,S), Bi3(Te,S)2,Bi(S,Te)2, and Bi8(S,Te)5. These probably correspond to ingodite, tetradymite (high and low S versions), and joseite. Where gold is rimmed or otherwise associated with Bi+BiTeS, the fineness is 960-980. In contrast, where gold is rimmed or otherwise associated with Bismuthenite (Bi2S3), the fineness varies from 960 to 870. Rare calcite associated with Bi2S3 indicates that this and low fineness gold were at relatively low temperature. These mineralogical variations suggest that gold—initially deposited as Au2Bi—was remobilized at successively lower temperatures and higher fS2 to gradually produce 'gold' with high silver contents and Bi2S3. Although the Au and Bi change mineralogical forms over time, they stay associated. This explains the very strong Bi-Au assay correlations seen at Fort Knox (average ~ 20:1) and the weaker Au-Te and Au-Mo correlations.