LiMoO3(IO3): A New Molybdenyl Iodate Based on WO3‐Type Sheets with Large SHG Response.
2007
Abstract A novel lithium molybdenyl iodate, LiMoO 3 (IO 3 ), has been prepared by hydrothermal reactions at 170 °C. Its crystal structure has been determined from single-crystal X-ray data: space group P 2 1 , a = 5.4104(4) A, b = 5.3158(3) A, c = 9.0025(7) A, β = 106.863(6)°, Z = 2. LiMoO 3 (IO 3 ) is a new layered material containing [ Mo O 3 ( I O 3 ) ] 1 − anionic layers separated by Li + cations. The anionic layer has an unprecedented configuration consisting of WO 3 -type sheets “capped” by IO 3 − groups. The iodate groups have their stereochemically active nonbonded electron pairs align along the b -axis, which creates the polarity in the structure. Second-harmonic-generation measurements on LiMoO 3 (IO 3 ) display a response of about 4 × KH 2 PO 4 . DTA measurements demonstrate that LiMoO 3 (IO 3 ) is stable up to at least 430 °C. UV–vis diffuse reflectance spectrum of this compound shows a high degree of transparency from 1.1 to 2.8 eV and a band gap of about 2.8 eV.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
1
References
0
Citations
NaN
KQI