Synthesis of nanosheet-structured Na3V2(PO4)3/C as high-performance cathode material for sodium ion batteries using anthracite as carbon source

Abstract Recently, Na 3 V 2 (PO 4 ) 3 has shown great promise as cathode material for sodium-ion batteries. In this study, a series of carbon-modified Na 3 V 2 (PO 4 ) 3 (NVP/C) composites have been synthesized using anthracite as the carbon source. The NVP/C composite shows a nanosheet shape with a 3D continuously conductive network composed of carbon layer and carbon bump. The effect of anthracite dosage on the electrochemical performance of NVP/C has also been investigated. The results show that the NVP/C composite prepared with 10 wt% anthracite (NVP/C-10) exhibits the highest rate capability and a great cycle stability. Especially the NVP/C-10 electrode behaves an average capacity as high as 97 mAh g −1 at a high current rate of 10 C. Moreover, NVP/C-10 still delivers a high specific capacity of 97.5 mAh g −1 even after 800 cycles at 5 C, showing a very low capacity fading ratio of 0.012% per cycle. The excellent rate capability and cycle stability of NVP/C-10 can be ascribed to the synergistic effects of the nanosheet structure and the 3D continuously conductive network. Our results demonstrate that anthracite can be a promising carbon source for the preparation of NVP/C and other polyanion cathode materials as well.