Fabrication and electrogenerated chemiluminescence properties of uniform octahedral 8-hydroxyquinoline zinc (Znq2)

Abstract Well-defined octahedral Znq 2 has been synthesized via a facile solvothermal route. Field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) images show that the as-prepared product has an octahedral structure with an edge length of 2 μm. The reaction parameters, such as solvent, reaction time and temperature, play an important part in the morphology of the final product. A possible formation mechanism for octahedral Znq 2 is proposed. The as-prepared octahedral Znq 2 exhibits excellent electrogenerated chemiluminescence (ECL) behaviour.