On zero-field anisotropic static Kubo-Toyabe relaxation functions

For muons which have thermalized in the allowed stopping sites of a given crystal, zero-field static Kubo-Toyabe spin dynamics is expressed in terms of the crystal frame spherical harmonic coefficients of the local classical random magnetic field distributions associated with each stopping site. The resulting muon spin polarization involves nine observable relaxation functions which are the counter frame spherical tensor expansion coefficients of the second-rank dynamic motion tensor. These relaxation functions can be measured simultaneously using the skewed field technique for the same experimental conditions, that is, with a single apparatus and with a single crystal-counter frame orientation. The local field distributions of, in general, arbitrary symmetry are classical approximations to the magnetic field interactions between the spin of the muon and the spins of the nuclei associated with each site at which the muon has stopped. They are characterized by equating their moments with the quantal moments generated by the quantal magnetic fields. The observable consequences of the anisotropic second-order moments associated with the planar sites of hexagonal crystals are used as an illustration.