Facile synthesis of ellipsoid-like MgCo2O4/Co3O4 composites for strong wideband microwave absorption application

Abstract As the high-speed advance of electronics industry, the facile synthesis of electromagnetic wave (EMW) absorbing materials with strong absorption capability, wide bandwidth, and thin thickness are urgently needed but remain challenging. Herein, hierarchical ellipsoid-like MgCo2O4/Co3O4 composites have been effectively synthesized by a facile hydrothermal method followed by calcination process. Meanwhile, by tuning the calcination temperature not only the morphology but also the crystalline structure (CoCO3+MgCo2(OH)6 → MgCo2O4+Co3O4) of the samples were attained. Especially, profiting from the distinctive anisotropic structure and the synergistic effect of dielectric and magnetic loss as well as good impedance matching, the hierarchical MgCo2O4/Co3O4 composites calcined at 450 °C exhibited excellent EMW absorption property. The minimum reflection loss (RLmin) of −48.54 dB at 12.96 GHz with the thickness of 2.6 mm as well as the broad effective bandwidth (RL