新型化合物[（CH2）5NH2]6[P2Mo18O62]·5H2O的合成与表征

A new polyoxometalate, [(CH2)5NH2]6[P2Mo18O62]•5H2O has been synthesized using conventional method, and characterized by elemental analysis, JR and single-crystal X-ray diffraction. X-ray analysis shows that the Dawson structure is still reserved in the compound heteropolymolybdata and certain red-shift and blue-shift occur in its characteristic spectral band. It indicates that strong interactions and electrostatic transfer exist between ligand and receptor.