Exploring the Unexplored Practical and Alternative Synthesis of 3- (Trifluoromethyl)-Triazolopiperazine the Key Intermediate for Sitagliptin
2013
A new, scalable, and extremely simple approach to synthesize the title triazolopiperazine (VII), a key intermediate in the preparation of the potent dipeptidyl peptidase-IV inhibitor sitagliptin, as well as related 3-trifluoromethyltriazolopyridines is developed.
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