Refinement of the incommensurate structure of high quality Bi-2212 single crystals from a neutron diffraction study
1998
Abstract We report the results of the refinement of data collected by neutron diffraction from a large single crystal of Bi 2 Sr 2 CaCu 2 O 8+ x (Bi-2212) which has an incommensurately modulated superlattice. These results are important in locating the positions of the oxygen atoms and their modulation by using four-dimensional crystallographic analysis. The four-dimensional space group is found to be consistent with N Bbmb/111. We do not find excess oxygen but do observe large modulations in the oxygen associated with the bismuth ions in the lattice. This is consistent with the superconducting transition temperature of 91 K with a sharp 2 K width obtained from oxygen deficient “as-grown” crystals. Our overall weighted r -factor is 0.052 including up to second order satellites, which is better than other published results for both single crystals and powders, obtained from X-ray and neutron diffraction studies.
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