In-cell indirect electrochemical halogenation of pyrimidine bases and their nucleosides to 5-haloderivatives

Giovanni Palmisano,Bruno Danieli,Marco Santagostino,Bruno Vodopivec,Giorgio Fiori

In-cell indirect electrochemical halogenation of pyrimidine bases and their nucleosides to 5-haloderivatives

1992

Giovanni Palmisano
Bruno Danieli
Marco Santagostino
Bruno Vodopivec
Giorgio Fiori

Abstract Reaction of anodically generated “halonium” species (Lix or Bu 4 NX, LiClO 4 , MeCN, Pt/Pt; I 2 , LiClO 4 , MeCN ) with pyrimidine bases and their nucleosides leads to 5-halo compounds in good yields

Keywords:

Pyrimidine
Halogenation
Halonium ion
Deoxyribonucleoside
Electrochemistry
Nucleic acid
Regioselectivity
Ribonucleoside
Chemistry
Organic chemistry
Desoxyribonucleoside

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