Optimal migration route of Cu in HfO2
2014
The movement of Cu in a HfO 2 -based resistive random access memory (RRAM) device is investigated in depth by first-principle calculations. Thermodynamics analysis shows that the dominant motion of Cu tends to be along the[001] orientation with a faster speed. The migration barriers along different routes are compared and reveal that the[001] orientation is the optimal migration route of Cu in HfO 2 , which is more favorable for Cu transportation. Furthermore, the preferable HfO 2 growth orientation along[100], corresponding to Cu migration along[001], is also observed. Therefore, it is proposed that the HfO 2 material should grow along[100] and the operating voltage should be applied along[001], which will contribute to the improvement of the response speed and the reduction of power consumption of RRAM.
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