Silole allylic anions instead of silanides
2021
Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KOtBu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighbouring phenyl group, which then transfers a proton to the 2-position of the silole ring.
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