Phenyl-Group Exchange in Triphenylphosphine Mediated by Cationic Gold–Platinum Complexes—A Gas-Phase Mimetic Approach

The PPh3 ligands in the heterodinuclear AuPt complex [(Ph3P)AuPt(PPh3)3][BAr4F] (BAr4F = tetrakis[3,5-bis(trifluoromethyl)phenyl]borate) exhibit a high fluxionality on the AuPt core. Fast intramole...