Controlled Release of Phosphorus from Superabsorbent Phosphate-Bound Alginate-Graft-Polyacrylamide: Resistance to Soil Cations and Release Mechanism

Two controlled-released fertilizers of phosphorylated alginate grafted with polyacrylamide (P-Alg-g-PAM) were synthesized. Monoammonium phosphate (MAP) and diammonium phosphate (DAP) were reacted with a matrix of sodium alginate (Alg) and poly(vinyl alcohol) (PVA). The phosphorylated matrix was then grafted with acrylamide. The obtained fertilizer materials showed excellent water absorbance. The controlled-release behavior of phosphorylated alginate grafted with polyacrylamide (P-Alg-g-PAM) was investigated at normal pH and 25 °C. The fertilizer materials exhibited release of phosphorus up to 77% for the MAP sample and up to 57% for the DAP sample till the forty fifth day of the application at pH 7 and 25 °C. More importantly, when the release experiments were conducted in calcium chloride medium, the fertilizers were able to release phosphorus efficiently with slight decrease until the forty fifth day of the application, suggesting that the presence of Alg in the fertilizer formulation may help in extending the duration for which phosphorus is available to the plant.