In Situ Transmission Electron Microscopy Observation of Electrochemical Behavior of CoS2 in Lithium-Ion Battery
2014
Metal sulfides are a type of potential anode materials for lithium-ion batteries (LIBs). However, their electrochemical behaviors and mechanism during the charge and discharge process remain unclear. In the present paper, we use CoS2 as a model material to investigate their electrochemical process using in situ transmission electron microscopy (TEM). Two kinds of reaction behaviors are revealed. The pure CoS2 particles show a side-to-side conversion process, in which large and anisotropic size expansion (47.1%) occurs that results in the formation of cracks and fractures in CoS2 particles. In contrast, the CoS2 particles anchored on reduced graphene oxide (rGO) sheets exhibit a core–shell conversion process involving small and homogeneous size expansion (28.6%) and few fractures, which attributes to the excellent Li+ conductivity of rGO sheets and accounts for the improved cyclability. Single-crystalline CoS2 particle converts to Co nanocrystals of 1–2 nm embedded within Li2S matrix after the first lithia...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
33
References
106
Citations
NaN
KQI