Engineering of an Upconversion Luminescence Sensing Platform Based on the Competition Effect for Mercury-Ion Monitoring in Green Tea.

Accurately monitoring mercury ions (Hg2+) in food and agriculture-related matrixes (e.g., green tea) is of great significance to safeguard food safety. Here, we employed upconversion nanoparticles (UCNPs) and gold nanoparticles (AuNPs) to engineer a cysteine (Cys)-assisted anti-Stokes luminescence sensing platform (UCNPs-AuNPs) for precisely detecting residual Hg2+ in green tea through the competition effect. Initially, AuNPs could effectively quench the luminescence of UCNPs through the luminescence resonance energy transfer process, which was then interrupted by Cys-triggered AuNP aggregation via Au-S, thereby restoring UCNP luminescence. Interestingly, owing to the competition effect with AuNPs toward Cys, Hg2+ could weaken the luminescence restoring efficiency, achieving a Hg2+ concentration-dependent luminescence change. On this basis, a facile, reliable, and sensitive upconversion luminescence sensing platform for monitoring residual Hg2+ in green tea was successfully established. This study offers a novel insight into integrating the competition effect and anti-Stokes luminescence for food- and agriculture-related contaminant monitoring.