The Synthesis of (+)-Nemorensic Acid.
2010
The synthesis of (+)-nemorensic acid in nine steps is
described; key steps in the route were the stereoselective Birch reduction
of a substituted furan, and addition of allyltrimethylsilane to an oxonium
ion at C-5; an X-ray crystal structure of (−)-nemorensic acid
provided proof of the relative stereochemistry of the target.
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