Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

Lucy Van Dijk,Ruchuta Ardkhean,Mireia Sidera,Sedef Karabiyikoglu,Ozlem Sari,Timothy D. W. Claridge,Robert S. Paton,Stephen P. Fletcher

Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

2020

Lucy Van Dijk
Ruchuta Ardkhean
Mireia Sidera
Sedef Karabiyikoglu
Ozlem Sari
Timothy D. W. Claridge
Robert S. Paton
Stephen P. Fletcher

A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Keywords:

Kinetic isotope effect
quantum chemical
Computational chemistry
Reaction mechanism
Rhodium
Enantioselective synthesis
Chemistry
Coupling (electronics)
Allyl halides
Catalysis

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