Fabrication and properties of cordierite based glass/AlN composites by sol–gel and pressureless sintering

Abstract In this study, the effect of AlN content on the crystallization behavior of cordierite based glass, was firstly investigated. Results show that μ-cordierite appeared in the composites with high AlN content even at high temperatures, which implied that the AlN may broad the crystallization temperature range of μ-cordierite and depress the transformation of μ→α-cordierite. The crystallization temperature of α-cordierite was about 980 °C for the pure glass and the temperature increased with AlN content for composites, but the crystallization temperature of μ-cordierite had reverse trend. The composites owned excellent bending strength when the AlN content was 20 wt%. With increasing of AlN content, the dielectric loss was increased which was caused mainly by the structural loss and the appearance of μ-cordierite, but the dielectric constant had crosscurrent. It was observed that the composites were beneficial in producing LTCC material which can be highlighted with high strength, low shrinkage and good dielectric properties at 1 MHz.