Highly Regioselective Pinacol Rearrangement of Sulfenylmethylated Glycols
1992
Pinacol rearrangement of glycols having a sulfenylmethyl group smoothly proceeded with high regioselectivity to give ketones which were derived by the elimination of the β hydroxyl group to the sulfur atom. This selectivity is due to the neighboring group participation of the sulfenyl group.
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