Total synthesis of FK-156 isolated from a Streptomyces as an immunostimulating peptide: application of a novel copper chelate amino protection

Keiji Hemmi,Hidekazu Takeno,Satoshi Okada,Osamu Nakaguchi,Yoshihiko Kitaura,Masashi Hashimoto

Total synthesis of FK-156 isolated from a Streptomyces as an immunostimulating peptide: application of a novel copper chelate amino protection

1981

Keiji Hemmi
Hidekazu Takeno
Satoshi Okada
Osamu Nakaguchi
Yoshihiko Kitaura
Masashi Hashimoto

Das Derivat (I) (Darstellung beschrieben) der entsprechenden (synthetisch zuganglichen) meso-Diamino-pimelinsaure wird enzymatisch hydrolysiert; selektiver Schutz der Aminogruppen im Produkt (IIa) unter Cu-chelat-Bedingungen liefert die Verbindung (IIb).

Keywords:

Chemistry
Streptomyces
Chelation
Peptide
Organic chemistry
Copper
Total synthesis

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